This article discusses the discovery of phosphorescent lithopone on watercolor drawings by American artist John La Farge dated between 1890 and 1905 and the history of lithopone in the pigment industry in the late 19th and early 20th centuries. Despite having many desirable qualities for use in white watercolor or oil paints, the development of lithopone as an artists’ pigment was hampered by its tendency to darken in sunlight. Its availability to, and adoption by, artists remain unclear, as colormen's trade catalogs were generally not explicit in describing white pigments as containing lithopone. Further, lithopone may be mistaken for lead white during visual examination and its short-lived phosphorescence can be easily missed by the uninformed observer. Phosphorescent lithopone has been documented on only one other work-to-date: a watercolor by Van Gogh. In addition to the history of lithopone's manufacture, the article details the mechanism for its phosphorescence and its identification aided by Raman spectroscopy and spectrofluorimetry.
2. Mentality: the buyer has to prepare goods in advance, and the new order price is slightly less willing to purchase in bulk; Because the seller's inventory is small, the manufacturer has no willingness to reduce the price of sales.Trend: The load of titanium dioxide enterprises is stable, the willingness to ship at low prices is not strong, and the downstream buyers place orders in the early stage to establish inventory, and the short-term supplementary orders after the holiday are less. Anatase titanium dioxide due to the overall volume of the market supply side is less, the space for quotation negotiation is small, and the focus of new orders will move up. It is expected that the titanium dioxide market today just needs to be closed, and the market trading atmosphere is relatively light.
Wegman’s puts titanium dioxide in its Original Macaroni and Cheese. Campbell’s Healthy Request Chunky Chicken Corn Chowder has it, as does Food Club’s Chunky New England Clam Chowder. Marzetti uses the color agent to brighten its Cream Cheese Fruit Dip. Dairy products usually don’t need titanium dioxide to look white, but Kroger has decided to add titanium dioxide to its Fat Free Half-and-Half. And titanium dioxide isn’t only in especially white or brightly colored foods: Little Debbie adds it to Fudge Rounds and many other products. According to the Food Scores database maintained by Environmental Working Group, more than 1,800 brand-name food products have titanium dioxide on their ingredients list. That said, it can still lurk as an unspecified “artificial color,” or labels might simply say “color added.”
Of the products that include the additive in their labels, Thea Bourianne, senior manager at data consultant Label Insights, told Food Navigator USA in May 2021 that more than 11,000 products in the company's database of U.S. food and beverage products listed titanium dioxide as an ingredient. Non-chocolate candy led those numbers at 32%. Cupcakes and snack cakes made up 14%, followed by cookies at 8%, coated pretzels and trail mix at 7%, baking decorations at 6%, gum and mints at 4% and ice cream at 2%.
The skin of an adult person is, in most places, covered with a relatively thick (∼10 μm) barrier of keratinised dead cells. One of the main questions is still whether TiO2 NPs are able to penetrate into the deeper layers of the skin. The majority of studies suggest that TiO2 NPs, neither uncoated nor coated (SiO2, Al2O3 and SiO2/Al2O3) of different crystalline structures, penetrate normal animal or human skin. However, in most of these studies the exposures were short term (up to 48 h); only few long-term or repeated exposure studies have been published. Wu et al.83 have shown that dermal application of nano-TiO2 of different crystal structures and sizes (4–90 nm) to pig ears for 30 days did not result in penetration of NPs beyond deep epidermis. On the other hand, in the same study the authors reported dermal penetration of TiO2 NPs with subsequent appearance of lesions in multiple organs in hairless mice, that were dermal exposed to nano-TiO2 for 60 days. However, the relevance of this study for human exposure is not conclusive because hairless mice skin has abnormal hair follicles, and mice stratum corneum has higher lipid content than human stratum corneum, which may contribute to different penetration. Recently Sadrieh et al. performed a 4 week dermal exposure to three different TiO2 particles (uncoated submicron-sized, uncoated nano-sized and coated nano-sized) in 5 % sunscreen formulation with minipigs. They found elevated titanium levels in epidermis, dermis and in inguinal lymph nodes, but not in precapsular and submandibular lymph nodes and in liver. With the energy dispersive X-ray spectrometry and transmission electron microscopy (TEM) analysis the authors confirmed presence of few TiO2 particles in dermis and calculated that uncoated nano-sized TiO2 particles observed in dermis represented only 0.00008 % of the total applied amount of TiO2 particles. Based on the same assumptions used by the authors in their calculations it can be calculated that the total number of particles applied was 1.8 × 1013 /cm2 and of these 1.4 x107/cm2 penetrated. The surface area of skin in humans is around 1.8 m2 and for sun protection the cream is applied over whole body, which would mean that 4 week usage of such cream with 5 % TiO2 would result in penetration of totally 2.6 × 1010 particles. Although Sadrieh et al.concluded that there was no significant penetration of TiO2 NPs through intact normal epidermis, the results are not completely confirmative.
Friends of the Earth revealed new testing results from the Australian Government’s National Measurement Institute, which found that many popular sunscreen and cosmetic products are using a potentially hazardous form -- anatase titanium dioxide. Six of the eight products tested, including well-known brands such as Nivea, L'Oreal, and CoverGirl, were found to contain this ingredient. (2)
Titanium Dioxide (TiO2) is a commonly used white pigment in paints due to its excellent whiteness, brightness, and weather resistance. It is also known for its ability to absorb ultraviolet light, which can help protect paint from fading and yellowing caused by sunlight. When TiO2 is used in paint, it is typically ground into a fine powder and then mixed with the other ingredients to create the final paint product. The amount of TiO2 used in paint can vary depending on the desired level of whiteness and opacity. In general, paints that are designed for outdoor use, such as exterior house paint, will contain higher levels of TiO2 than paints that are intended for indoor use. One of the main advantages of using TiO2 in paint is its ability to provide a durable and long-lasting finish. This is because TiO2 is very resistant to weathering and does not easily break down or fade when exposed to the elements. As a result, paints that contain TiO2 can provide excellent protection against the effects of sunlight, rain, and other environmental factors. Another advantage of TiO2 is its low cost compared to other pigments. This makes it an attractive option for manufacturers who want to produce high-quality paint at an affordable price This makes it an attractive option for manufacturers who want to produce high-quality paint at an affordable price
This makes it an attractive option for manufacturers who want to produce high-quality paint at an affordable price This makes it an attractive option for manufacturers who want to produce high-quality paint at an affordable pricetio2 used in paint. However, the cost of TiO2 can vary depending on factors such as the quality of the raw material and the production process. In recent years, there has been some concern about the potential health risks associated with exposure to TiO2 dust. While studies have shown that TiO2 is generally considered safe for human contact, there is still some debate about the long-term effects of inhaling TiO2 particles. As a result, many manufacturers are now looking for alternative pigments that can provide similar levels of performance without the same health risks. Overall, Titanium Dioxide is a versatile and widely used pigment in the paint industry. Its ability to provide a durable and long-lasting finish, coupled with its low cost, make it an attractive option for manufacturers and consumers alike. However, as concerns about health risks continue to be studied, it is likely that we will see more research into alternative pigments that can provide similar benefits without the same potential health risks.
These minerals can improve the tear strength, abrasion resistance, and flexibility of rubber materials These minerals can improve the tear strength, abrasion resistance, and flexibility of rubber materials
Others are looking into recycling waste streams from the manufacturing process to recover titanium compounds, thus closing the loop on material use Others are looking into recycling waste streams from the manufacturing process to recover titanium compounds, thus closing the loop on material use